Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides.
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چکیده
منابع مشابه
Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes.
Monomeric, three-coordinate arylpalladium(II) halide complexes undergo reductive elimination of aryl halide to form free haloarene and Pd(0). Reductive elimination of aryl chlorides, bromides, and iodides were observed upon the addition of P(t-Bu)3 to Pd[P(t-Bu)3](Ar)(X) (X = Cl, Br, I). Conditions to observe the equilibrium between reductive elimination and oxidative addition were established ...
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ورودعنوان ژورنال:
- Angewandte Chemie
دوره 46 40 شماره
صفحات -
تاریخ انتشار 2007